Oil Regeneration Process
THE ECONOMIC & ENVIRONMENTAL SOLUTION
Transformers are the single most expensive item of high voltage plant in a substation. It is a recognised fact that deterioration of transformer oil, through either oxidation and/or contamination, can cause premature and at times catastrophic failure. Similarly oil will deteriorate at a greater rate as a transformer is operated at progressively higher loads.
Traditionally, transformers have been designed with reasonable overload capacity and conservatively loaded. Recent moves towards corporatisation/privatisation of electrical utilities, and the inevitable economic constraints that go with that, demand tighter design criteria and enhanced performance from network assets. Loading of transformers has increased with an attendant need to endure maximum integrity of performance.
It makes good economic sense, and gives confidence when loadings are increased, to regularly test and maintain transformer oil in good condition.
The normal aging process of a transformer results in sludge formation. It will appear faster in a heavily loaded, hot running transformer. The formation of sludge can be further hastened by the presence of moisture and free access to oxygen. Sludge builds up in progressive layers with varying degrees of hardness depending on how the unit has been operated.
Acids are first formed in the oil by the oxidation of its components, and the rate of build up of acid formation is an exponential one. After a significantly high concentration of acids has occurred they then attack the iron, copper, varnishes, paints and cellulose insulation. These materials coming into solution combine to form sludge.
Sludge then precipitates out of solution and forms a heavy tarry substance, which adheres to the insulation, the sidewalls of the tank, the core, and lodges in ventilating ducts and cooling fins. Sludges are also formed in the cellulose fibres of the insulating system itself.
Sludges, once deposited on the insulation and formed in the insulation system, immediately go to work to increasingly leech out varnishes and cellulose materials from the insulation, resulting in severe shrinkage of the insulation.
Since formation of sludge is one of the prime causes for premature failure, it was imperative that a solution be found to remedy the problem.
ON-SITE OIL RECLAMATION AND TRANSFORMER CONDITIONING
Reclamation of transformer oil is energy efficient and less expensive today than refilling an older transformer with new oil. Further, it must be appreciated that simply replacing poor quality oil with newer, or reclaimed oil is not the answer, as the oil will in turn, rapidly deteriorate due to re-contamination by internal components of the transformer. The complete solution is not just simple reclamation of transformer oil – the sludges must be dissolved and removed from the transformer itself.
Regeneration of oil and desludging of transformers has been carried out successfully in overseas countries for many years using a well proven technique of hot oil purging and filtering via Fuller’s Earth adsorbent bed. (Adsorption is the tendency of a liquid, gas or small particle to cling to the surface of another substance by physical rather than chemical means.).
Most of the contaminants in oil, including water, are polar in nature and are therefore easily adsorbed. There are several types of adsorbent material, the most widely used and accepted is Fuller’s Earth, with alternatives such as activated alumina and molecular sieves being less attractive and far more expensive.
Transformer oil itself can be reclaimed in one pass through a Fuller’s Earth bed of proper size and utilisation. Additional passes of hot oil redissolve decay products in and on the transformer insulation, core and coils, thus effectively scrubbing out the vital parts of the transformer.
The number of recirculations through the filtering system to accomplish internal cleaning of a transformer depends on a number of factors, including the:
Quality and quantity of Fuller’s Earth
Condition of the oil
Age of transformer
It is recommended that hot oil cleaning should occur before an acidity level (Neutalisation Number (NN)) of 0.15mg KOH/gm and an Interfacial Tension (ITF) of 24dynes/cm is reached. These figures represent the maximum oil degradation beyond which the oil is unable to keep the sludges in solution.
When oil test indicate an acidity level greater than 0.3mg KOH/gm and an IFT less than 17.9dynes/cm, complete desludging procedures are required.
It is recommended that the desludging process takes place with the transformer energised – the mechanical vibration helps the hot oil dissolve sludges in the innermost recesses of the insulating system while the heat from the copper and iron losses aids in the general heating of the oil. The following table is used as guide to determine the appropriate number of passes required to recondition a given transformer:
A NEW PROCESS
The major drawback of traditional oil reclamation and desludging techniques is the enormous waste product generated that has to be disposed of. For example, a transformer containing some 50, 000 litres of oil with initial and final NN’s of 0.2 and 0.03 respectively would require approximately 5,000 kg of Fuller’s Earth. After the regeneration process, approximately 8, 000 kg of waste in the form of oily Fuller’s Earth, saturated with contaminants has to be removed from the transformer site and disposed of.
In most countries, the disposal of oily Fuller’s Earth, as land refill, is now banned. This is simply because the 8 tonnes of waste as demonstrated above will contain approx. 3000kg of contaminated oil, which reportedly can pollute 150,000 m3 of water.
The ESI Group has invested in new and innovative technology which has specially treated Fuller’s Earth permanently installed within the regeneration plant for approximately 4 years (approx. 500 reactivations). When the Fuller’s Earth becomes inefficient in adsorption of contaminants, it is then reactivated within the plant, without removal from the percolating columns.
It should be stressed that reactivation of Fuller’s Earth within the ESI plants is carried out within the percolating columns, fully automatic, without assistance from the operator. It takes less than 16 hours to reactivate the Fuller’s Earth in the columns. Before the commencement of reactivation, excess oil is removed from the Fuller’s Earth. This is accomplished by a heat and air purge. The reactivation process is carried out as a combination heat wave, vacuum drying and solvent action. After a successful completion of the reactivation process, the Fuller’s Earth is completely dry and does not contain any residual oil or solvent. Finally, after it can no longer be efficiently reactivated, the Fuller’s Earth can be disposed of with no environmental problems whatsoever.
MAIN FEATURE OF ESI SYSTEM
Fuller’s Earth type LVM 60/90 which is commonly used in earlier technology oil reclamation systems, is not suitable for reactivation. Hardened grades such as RMV, Porocel and Tonsil can be reactivated up to 500 times. A number of grades of Fuller’s Earth are mixed in the ESI system to provide a balanced and optimum treatment of oil with respect to acidity correction, discolouration, improvement of dissipation factor and rehabilitation of many other properties.
The Reclamation plants used by ESI are known as mobile generation plants, they have multiple regeneration columns and flow rates of 1 - 6,000 litres/hr (MRP6) and 1 – 2,000 litre/hr (MRP2).
Reclamation, degassing and reactivation operations are all controlled by a programmable Logic Controller and monitored by a computer, which will be located within the plant. This high degree of automation ensures a maximum safety, reliability and simpli city of operation. All vital operating parameters are read, monitored and adjusted according to program, and stored on hard disk for retrieval as and when required.
OIL QUALITY AND TRANSFORMER LIFE EXTENSION
ESI guarantee of oil quality on completion of reclamation would include :
ACIDITY max 0.03 mgKOH/g
INTERFACIAL TENSION min 40 dynes/cm
DIELECTRIC STRENGTH min 60 KV
MOISTURE max 10ppm
INHIBITOR (DBPC) min 0.25%
New oil contains natural inhibitors, which are consumed during the normal aging process, and as a result reclaimed oil will oxidise, or age, at a faster rate than new oil. For this reason it is extremely important to add an inhibitor (the most common inhibitor being DBPC) to minimise the rate of oxidation of the reclaimed oil.
Independent studies by SD Myers and Hydro-Quebec have shown that optimum time to reclaim and re-inhibit oil is not at the time when the inhibitor has been fully depleted, but prior to the oil showing signs of aging as measured by acidity, IFT and other classic tests.
In summary: it is vital to keep transformers in good condition by maintaining the oil in good condition. This is achieved by carrying out regular condition monitoring tests and where indicated, by regenerating and inhibiting the oil.
ECOLOGY AND ECONOMY
There are a number of very distinct advantages in reclaiming oil with a reactivatable Fuller’s Earth system: The residue created in the process of oil reclamation is negligible (less then 0.1%) but is still reuseable. (In the process of reactivation, the contaminants are removed from the Fuller’s Earth and concentrated within a small quantity of transformer oil. This oily residue can be used as feedstock in engine oil re-refining plants). Oil loss is minimal compared to previous technologies, less than 0.2% of reclaimed volume. Transformer oil is becoming a scarce resource and its’ recycling as opposed to replacement makes sound economic and environmental sense now and in the future. Fuller’s Earth is also a valuable resource and reactivation within the columns extends its’ life 500 times The new reclamation system is economical to run in comparison to existing types of reclamation.
PROTECTION AGAINST OIL SPILLAGE
All ESI plants offer a high degree of reliability with respect to spillage protection during operation. Any oil leakage from various interface devices such as relief valves, de-aerators, vacuum pumps etc, is monitored by level sensing devices and any spillage is contained within the fully bunded plants. If there is an indication of an oil spillage, the plants will shutdown immediately and automatically isolate themselves from the oil supply.